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where is the electrical resistivity, l the length of the resistor in the direction of the electric current, A the cross section traversed by electric current, and w and t the width and height of a rectangular cross-section Accordingly, small resistances can be realised with materials having high electrical conductivity, such as metals However, extremely thin metal layers have to be used when higher values of resistance are required In addition, for local heating, supply lines to the heaters must be signi cantly wider and thicker in size to prevent parasitic heating Hence, for metal heaters operating in the lower voltage range, their layer thicknesses have to be in the nm range This requires precise control of thickness and speci c resistivity of the metal by its deposition method, including recrystallisation effects at high temperatures.

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Phase changes imply structural modi cations, which may also result in the generation of intrinsic stresses Passivation is needed to prevent oxidation, which again changes the overall resistivity and may render the entire lm insulating with time In semiconductors, electrical conductivity is controlled by doping Highly doped or quasi-metallically doped semiconductors usually exhibit three orders of magnitude higher resistivity values than metals Thus, for the same heater surface dimensions, layer thicknesses can be increased from the nm range into the m range, enabling tighter control and reproducibility Wiring of such semiconductor heater elements can then be realised by metal lines with negligible self-heating In many semiconductors, chemical instabilities (like phase changes) and corrosion (through oxidation or etching) are observed In contrast, nanocrystalline diamond lms are highly stable No change in phase has been observed even under operation at 1000 C (in vacuum).

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Many orogens are composed of a collage of faultbounded blocks that preserve geologic histories unrelated to those of adjacent blocks. These units are known as terranes and may range in size from a few hundreds to thousands of square kilometers. Terranes usually are classi ed into groups according to whether they are native or exotic to their adjacent continental cratons (e.g. Section 11.5.5). Exotic (or allochthonous) terranes are those that have moved relative to adjacent bodies and, in some cases, have traveled very great distances. For example, paleomagnetic investigations have demonstrated that some terranes have a north south component of motion of several thousand kilometers (Beck, 1980; Ward et al., 1997) and have undergone rotations of up to 60 (Cox, 1980; Butler et al., 1989). The boundaries of terranes may be normal, reverse, or strike-slip

In air, oxidation (and etching) of grain boundaries is known to start at about 600 C [43], before the grains themselves are attacked In water, microcrystalline diamond is used as electrochemical electrode in electroanalysis with high anodic overpotentials, or in waste water treatment without degradation over an extended period of time (see 17 by Foord in this book) Obviously, the performance will depend on the graphitic grain boundary content of the lm and UNCD may be less stable than NCD or microcrystalline lms NCD heaters have been used in contact with acidic and alkaline solutions, withstanding for example the ejection of H2 SO4 in a bubble-jet con guration without degradation Figure 181 illustrates the use of a diamond heater element working as a microfountain by applying a microsecond electrical pulse (in the case shown with a power density close to 1 MW/cm2 ) to the heater.

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The height of the water column was about 20 cm [17, 44] Such types of heater have been the heart of diamond bubble-jet devices (see Section 18432) To obtain high electrical conductivity in nanocrystalline diamond lms, two possible doping schemes can be considered One is doping with boron Boron acts as an acceptor within the diamond grains (see s 3 by Mainwood and 2 by Isberg in this book) and can be also incorporated within the grain boundaries In the crystal bulk it is a deep acceptor with an activation energy of 370 meV [45] However, at a concentration above about 1019 cm 3 the activation energy is reduced by miniband formation (see Figure 182) This activation energy is, in many cases, also preserved in NCD lms.

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